Physical Properties of Ore Minerals

Table 4. Monoclinic Crystal Class

© Charles E. Corry

Minerals are arranged alphabetically by space group (Schoenflies symbol).

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Mineral NameCompositionSpace GroupResistivity (ohm-m)Dielectric PermittivityCharge Separation PhenomenaCurie Temp. °CMagnetic Properties k×10-6cgsOptical PropertiesR %Comments
ColemaniteCaB3O4(OH)3·H2O
Ca2B6O11·5H2O
C22insulator
3×1010
14<e<7,000ferroelectric
Goldsmith (1956)
-7 moderate birefringenceOTParaelectric, space group C2h5at normal temperatures.
Dufrénoysite2PbS·As2S3C22  ferroelectric ?
(isostructural)
  very weak pleochroism, distinct anisotropy, very weak bireflectance.36.1 to 39.4 
Liveingite
(rathite II)
Pb9As13S20C22  ferroelectric ?
(isostructural)
  weak bireflectance, distinct anisotropy.34.0 to 36.0 
Wakabayashilite(As10·2Sb)S18
As11S18
C22  pyroelectric
ferroelectric ??
  strongly anisotropic, very bright internal reflections.||a ~26?
||b ~18?
Ramdohr (1980) says orthorhombic crystal class if As11S18.
ParadocrasiteSb2(Sb,As)2C23metal pyroelectric   70 ? 
PolybasiteAg16Sb2S11C2?  pyroelectric
Parkhomenko (1971)
  distinct pleochroism in oil, strongly anisotropic, abundant internal reflections, weak to distinct bireflectance.R1-32.6
R2-30.7
 
SylvaniteAuAgTe4C2h4metal ?
4×10-6 to 2×10-5
 ferroelectric ??  very distinct pleochroism, very strong anisotropy, common twinning, distinct bireflectance.R1-50.3
R2-59.0
Most common gold telluride.
Wolframite(Fe,Mn)WO4C2h4semiconductor
10 to 105
 ferroelectric ??  weak pleochroism, weak to distinct anisotropy, weak to distinct bireflectance, moderate birefringence.R1-15.0
R2-16.2
 
Acanthite
(argentite)
Ag2SC2h5semiconductor
n-type
1.5×10-3 to 1.5
>81ferroelectric ?
(isostructural)
179°diamagnetic
k = -30
very weak pleochroism, distinctly anisotropic, weak bireflectance.R1-30.3
R2-31.3
Converts to argentite, cubic, space group Oh9, at 179° and resistivity drops three orders of magnitude.
ArsenopyriteFeAsS
As2S3
C2h5semiconductor
mixed type
10-5 to 20
7 to >81ferroelectric ?
(isostructural)
<500diamagnetic or paramagnetic
k = 240
weak pleochroism, strongly anisotropic, weak bireflectance.Ra-52.2
Rb-51.7
Rc-52.0
Forms solid solution with pyrrhotite. Isostructural with Pb3(VO4)2 and Pb3(AsO4)2.
AzuriteCu3(OH)2(CO3)2C2h5semiconductor
5.6×108
6<e<21ferroelectric ?
(isostructural)
  internal reflections so strong they mask strong anisotropy, strong bireflectance, extreme birefringence.OT
~8
 
BaddeleyiteZrO2C2h5 12.4ferroelectric ?
(isostructural)
 diamagnetic
k = -14
weak anisotropy, weak to moderate birefringence.13 to 14 
BaumhaueritePb3As4S9C2h5  ferroelectric ?
(isostructural)
  distinct pleochroism, strong anisotropy, abundant twin lamellae, distinct bireflectance.35.8 to 40.2 
BoulangeritePb5Sb4S11C2h5semiconductor
2×103 to 4×105
 ferroelectric ?
(isostructural)
  weak pleochroism, strong anisotropy, distinct bireflectance.R1-38.3
R2-43.5
Forms solid solution with falkmanite.
ChalcociteCu2SC2h5semiconductor
p-type
10-4 to 2.3×103
>81ferroelectric
Bieniulis (1985),
Bieniulis et al. (1984, 1987)
105 to 130diamagneticvery weak pleochroism, weakly to distinctly anisotropic, very weak bireflectance.Ra-33.5
Rb-33.2
Various dimorphic and non-stoichiometric forms. Optical properties vary greatly with composition. Measurable surface charges on crystal faces at 25C. Pseudo-orthorhombic.
DiaphoritePb4Ag6Sb6S16C2h5  ferroelectric
(isostructural)
  distinct bireflectance, strong anisotropy, no internal reflections.37.2 to 40.6 
FreieslebenitePbAgSbS3C2h5  ferroelectric
(isostructural)
  very weak pleochroism, distinct anisotropy but lower than in similar minerals, weak bireflectance.R1-39.5
R2-35.6
 
GudmunditeFeSbSC2h5  ferroelectric
(isostructural)
  very distinct pleochroism, strongly anisotropic, distinct bireflectance.50.1 to 55.2 
HessiteAg2TeC2h5semiconductor
10-6 to 10-4
 ferroelectric ?
(isostructural)
  distinct pleochroism in oil, strong anisotropy, weak bireflectance.37.5 
JamesonitePb4FeSb6S14C2h5semiconductor
10-2 to 0.1
 ferroelectric ?
(isostructural)
  very distinct pleochroism intense anisotropy, twinning ||(100) characteristic, strong bireflectance.R1-37.4
R2-42.9
 
LivingstoniteHgSb4S7C2h5  ferroelectric ?
(isostructural)
  fair pleochroism, very strong anisotropy, abundant internal reflections, distinct bireflectance.30.3 to 39.5Crystal system is controversial. May be triclinic?
LoranditeTlAsS2C2h5  ferroelectric ?
(isostructural)
  weak pleochroism, strong anisotropy may be masked by internal reflections, weak bireflectance.26.9 to 29.5 
MalachiteCu2(OH)2CO3C2h5insulator
109
4<e<6ferroelectric ?
(isostructural)
  abundant internal reflections mask strong anisotropy, strong bireflectance, extreme birefringence.OT
~8
 
ManganiteMnO(OH)C2h5semiconductor
10-2 to 0.5
 ferroelectric ?
(isostructural)
  weak pleochroism, ||(001), distinct pleochroism ||(010) and (100), quite vivid anisotropy, striking internal reflections ||(010) plane, weak to distinct bireflectance, moderate birefringence.R1-14.8
R2-20.7
 
MarritePbAgAsS3C2h5  ferroelectric ?
(isostructural)
  distinct anisotropy, common internal reflections.31.5 to 34.0 
NitrokaliteCa(H2O)(NO3)2C2h5  ferroelectric
Parkhomenko (1971)
  no data  
OrpimentAs2S3C2h5  ferroelectric ?
(isostructural)
 diamagnetic
k = -70
very strong pleochroism, internal reflections mask very strong anisotropy, strong bireflectance, extreme bireflectance.R1-27.5
R2-23.0
 
Quenselite2PbO·Mn2O3C2h5  ferroelectric ?
(isostructural)
  moderate pleochroism, strong anisotropy, common internal reflections, distinct bireflectance.20.7 to 23.2 
RealgarAsSC2h5  ferroelectric ?
(isostructural)
  strong anisotropy, very abundant internal reflections, weak to distinct bireflectance, extreme birefringence.R1-22.1 
Rathite(Pb,Tl)3As5S10C2h5  ferroelectric ?
(isostructural)
  strong pleochroism, extreme anisotropy, distinct bireflectance.R1-41.4
R2-35.0
 
SamsoniteAg4MnSb2S6C2h5  ferroelectric ?
(isostructural)
  weak pleochroism, weak anisotropy, distinct bireflectance.29.8 to 30.8 
Sartorite
(scleroclase)
PbAs2S4C2h5  ferroelectric ?
(isostructural)
  strong anisotropy, widespread twinning.R1-36.9
R2-33.6
 
SulfurSC2h5insulator
105 to 1016
mean 1012
3.8ferroelectric ?
(isostructural)
<119diamagnetic
k = -15
distinct pleochroism, distinct anisotropy masked by omnipresent internal reflections, distinct bireflectance, extreme birefringence.||a 10.5
||b 11.7
||c 14.7
No elements are presently known to form ferroelectric crystals.
MiagyriteAgSbS2C2h6  ferroelectric ??  distinct pleochroism, strong anisotropy, distinct bireflectance.R1-34.5
R2-31.6
 
TenoriteCuOC2h6semiconductor18.1ferroelectric ?? antiferromagnetic
k = 250
Tn = -43°C
moderate to strong pleochroism, distinct to strong anisotropy, distinct bireflectance.R1-21.1
R2-25.7
 
Titanite
(sphene)
CaTi(O/SiO4)C2h6insulator
1.7×1011
21ferroelectric ??  extreme birefringence, pleochroic in reflected light.OT to ~10 


Ore Minerals - 29 JAN 1997

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